|
|
(S)-3-hydroxybutyryl-CoA <=> (3R)-hydroxybutyryl-CoA
|
5.1.2.3
3-hydroxybutyryl-CoA epimerase
|
–
|
K
|
|
BRENDA:
BR180
KEGG:
R03276
MetaCyc:
5.1.2.3-RXN
|
|
|
|
(3R)-hydroxybutyryl-CoA <=> crotonyl-CoA + H2O
|
4.2.1.119
enoyl-CoA hydratase 2
4.2.1.150
short-chain-enoyl-CoA hydratase
4.2.1.17
enoyl-CoA hydratase
4.2.1.55
3-hydroxybutyryl-CoA dehydratase
4.2.1.59
3-hydroxyacyl-[acyl-carrier-protein] dehydratase
|
–
–
–
–
–
|
BMK
|
|
BRENDA:
BR433;
BS18665
KEGG:
R03027;
R05595
MetaCyc:
3-HYDROXBUTYRYL-COA-DEHYDRATASE-RXN
SABIO-RK:
2877;
5195
|
|
|
|
(3R)-hydroxybutyryl-CoA + NADP+ <=> acetoacetyl-CoA + NADPH + H+
|
1.1.1.100
3-oxoacyl-[acyl-carrier-protein] reductase
1.1.1.157
3-hydroxybutyryl-CoA dehydrogenase
1.1.1.36
acetoacetyl-CoA reductase
|
–
–
–
|
BMK
|
|
BRENDA:
BS188074;
BS383049
KEGG:
R01977;
R05576
MetaCyc:
RXN-5901
SABIO-RK:
5178
|
|
|
|
(3R)-hydroxybutyryl-CoA + H2O <=> (R)-3-hydroxybutanoate + CoA + H+
|
3.1.2.2
palmitoyl-CoA hydrolase
3.1.2.20
acyl-CoA hydrolase
3.1.2.4
3-hydroxyisobutyryl-CoA hydrolase
|
–
–
–
|
M
|
|
BRENDA:
BS360747
MetaCyc:
RXN-14255
SABIO-RK:
12736
|
|
|
|
n (3R)-hydroxybutyryl-CoA <=> poly(3-hydroxybutanoate)n + n CoA
|
2.3.1
|
–
|
K
|
|
KEGG:
R04254
|
|
|
|
(3R)-hydroxybutyryl-CoA + poly(3-hydroxybutanoate)n <=> poly(3-hydroxybutanoate)n + CoA
|
2.3.1.dq
|
–
|
M
|
|
MetaCyc:
RXN1-42
|
|
|
|
acetoacetyl-CoA + NADH <=> (3R)-hydroxybutyryl-CoA + NAD+
|
1.1.1.36
acetoacetyl-CoA reductase
|
–
|
|
|
BRENDA:
BS369971
|
|
|
|
(3R)-hydroxybutyryl-CoA + NAD+ <=> 3-oxobutylryl-CoA + NADH
|
1.1.1.36
acetoacetyl-CoA reductase
|
–
|
|
|
BRENDA:
BS383442
|
|
|
|
(3R)-hydroxybutyryl-CoA + [(R)-3-hydroxybutanoate]n <=> [(R)-3-hydroxybutanoate](n+1) + CoA
|
2.3.1.B2
2.3.1.B3
2.3.1.B4
|
–
–
–
|
|
|
BRENDA:
BR48953
|
|
|
|
(3R)-hydroxybutyryl-CoA <=> 2-hydroxy-2-methylpropanoyl-CoA
|
5.4.99.64
2-hydroxyisobutanoyl-CoA mutase
|
–
|
|
|
BRENDA:
BS434952
|
|
|
|
(Z)-2-butenoyl-CoA + H2O <=> (3R)-hydroxybutyryl-CoA
|
4.2.1.17
enoyl-CoA hydratase
|
–
|
|
|
BRENDA:
BS402300
|
|
|
|
(2E)-crotonyl-CoA + H2O <=> (3R)-hydroxybutyryl-CoA
|
4.2.1.119
enoyl-CoA hydratase 2
|
–
|
|
|
BRENDA:
BS444476
|
|
|
|
(3R)-hydroxybutyryl-CoA <=> 2-hydroxybutanoyl-CoA
|
5.4.99.64
2-hydroxyisobutanoyl-CoA mutase
|
–
|
|
|
BRENDA:
BS436656
|
|